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PRODUCT DETAILS
OTHER CHEMICALS > Sodium Silicate Liquid

A mixture of caustic soda, quartz sand, and water are prepared in a mixing tank, then fed into a reactor, where steam is introduced. The reaction is n SiO2 + 2 NaOH → Na2O•nSiO2 + H2O

Uses

In 1990, 4M tons of alkali metal silicates were produced. The main applications were in detergents, paper, water treatment, and construction materials.

Adhesive

The largest application of sodium silicate solutions is a cement for producing cardboard.[3] When used as a paper cement, the tendency is for the sodium silicate joint eventually to crack within a few years, at which point it no longer holds the paper surfaces cemented together.

Drilling fluids

Sodium silicate is frequently used in drilling fluids to stabilize borehole wells and to avoid the collapse of bore walls. It is particularly useful when drill holes pass through argillaceous formations containing swelling clay minerals such as smectite or montmorillonite.

Concrete and general masonry treatment

Concrete treated with a sodium silicate solution helps to significantly reduce porosity in most masonry products such as concrete, stucco, plasters. A chemical reaction occurs with the excess Ca(OH)2 (portlandite) present in the concrete that permanently binds the silicates with the surface making them far more durable and water repellent. It is generally advised to apply this treatment only after the initial cure has taken place (7 days or so depending on conditions). These coatings are known as silicate mineral paint.

Detergent auxiliaries

It is used in detergent auxiliaries like complex sodium disilicate and modified sodium disilicate. The detergent granules gain their ruggedness from a coating of silicates.

Water treatment

Water glass is used as coagulant/flocculant agent in waste water treatment plants. Waterglass binds to colloidal molecules, creating larger aggregates that sink to the bottom of the water column. The microscopic negatively charged particles suspended in water interact with sodium silicate. Their electrical double layer collapses due to the increase of ionic strength caused by the addition of sodium silicate (doubly negatively charged anion accompanied by two sodium cations) and they subsequently aggregate. This process is called coagulation/flocculation.

Refractory use

Water glass is a useful binder of solids, such as vermiculite and perlite. When blended with the aforementioned lightweight aggregates, water glass can be used to make hard, high-temperature insulation boards used for refractories, passive fire protection and high temperature insulations, such as moulded pipe insulation applications. When mixed with finely divided mineral powders, such as vermiculite dust (which is common scrap from the exfoliation process), one can produce high temperature adhesives. The intumescence disappears in the presence of finely divided mineral dust, whereby the waterglass becomes a mere matrix. Waterglass is inexpensive and abundantly available, which makes its use popular in many refractory applications.

Dye auxiliary

Sodium silicate solution is used as a fixative for hand dyeing with reactive dyes that require a high pH in order to react with the textile fiber. After the dye is applied to a cellulose-based fabric, such as cotton or rayon, or onto silk, it is allowed to dry, after which the sodium silicate is painted on to the dyed fabric, covered with plastic to retain moisture, and left to react for an hour at room temperature.

Niche and hobby uses

Expantrol proprietary sodium silicate suspended in an about 6.5 mm thick layer of red rubber, type 3M FS195, inserted into a metal pipe, then heated, to demonstrate hard char intumescence, strong enough to shut a melting plastic pipe.
Palusol based intumescent plastic pipe device used for commercial firestopping.

Sodium silicates are inherently intumescent. They come in prill (solid beads) form, as well as the liquid, water glass. The solid sheet form (Palusol) must be waterproofed to ensure long-term passive fire protection.

Standard, solid, bead form sodium silicates have been used as aggregate within silicone rubber to manufacture plastic pipe firestop devices. The silicone rubber was insufficient waterproofing to preserve the intumescing function and the products had to be recalled, which is problematic for firestops that are concealed behind drywall in buildings.

Pastes for caulking purposes are similarly unstable. This too has resulted in recalls and even litigation. Only 3M's "Expantrol" version, which has an external heat treatment that helps to seal the outer surface, as part of its process standard, has achieved sufficient longevity to qualify for DIBt approvals in the US for use in firestopping

Not unlike other intumescents, sodium silicate, both in bead form and in liquid form are inherently endothermic, due to liquid water in the water glass and hydrates in the prill form. The absence in the US of mandatory aging tests, whereby PFP systems are made to undergo system performance tests after the aging and humidity exposures, are at the root of the continued availability, in North America, of PFP products that can become inoperable within weeks of installation. Indiscriminate use of sodium silicates without proper waterproofing measures are contributors to the problems and risk. When sodium silicates are adequately protected, they function extremely well and reliably for long periods. Evidence of this can be seen in the many DIBt approvals for plastic pipe firestop devices using Palusol, which use waterproofed sodium silicate sheets.

Food preservation

World War I poster suggesting the use of waterglass to preserve eggs (lower right).

Sodium silicate was also used as an egg preservation agent through the early 20th century with large success. When fresh eggs are immersed in it, bacteria which cause the eggs to spoil are kept out and water is kept in. Eggs can be kept fresh using this method for up to five months. When boiling eggs preserved this way, it is well advised to pin-prick the egg to allow steam to escape because the shell is no longer porous.

Metal repair

Sodium silicate is used, along with magnesium silicate, in muffler repair and fitting paste. When dissolved in water, both sodium silicate, and magnesium silicate form a thick paste that is easy to apply. When the exhaust system of an internal combustion engine heats up to its operating temperature, the heat drives out all of the excess water from the paste. The silicate compounds that are left over have glass-like properties, making a temporary, brittle repair.

Automotive repair

Sodium silicate is also used currently as an exhaust system joint and crack sealer for repairing mufflers, resonators, tailpipes and other exhaust components, with and without fiberglass reinforcing tapes. In this application, the sodium silicate (60-70%) is typically mixed with kaolin (40-30%), an aluminium silicate mineral, in order to make the sodium silicate "glued" joint opaque. The sodium silicate, however, is the high temperature adhesive; the kaolin serves simply as a compatible high temperature coloring agent.

Sodium silicate can be used to fill gaps within the head gasket. Commonly used on aluminum alloy cylinder heads, which are sensitive to thermally induced surface deflection, and can be caused by many things including head-bolt stretching, deficient coolant delivery, high cylinder head pressure, over-heating, etc.

"Liquid glass" (sodium silicate) is added to the system through the radiator, and allowed to circulate. Sodium silicate is suspended in the coolant until it reaches the cylinder head. At 100–105 °C sodium silicate loses water molecules to form a glass seal with a re-melt temperature above 810 °C.

A sodium silicate repair will last two years, sometimes longer. The repair occurs rapidly, and symptoms disappear instantly. This repair only works when the sodium silicate reaches its "conversion" temperature at 100–105 °C. Contamination of engine oil is a serious possibility in situations in which a coolant-to-oil leak is present. Sodium silicate (glass particulate) contamination of lubricants is detrimental to their function.

Sodium silicate solution is used to inexpensively, quickly, and permanently disable automobile engines. Running an engine with about 2 liters of a sodium silicate solution instead of motor oil causes the solution to precipitate, catastrophically damaging the engine's bearings and pistons within a few minutes. In the United States, this procedure was used to comply with requirements of the Car Allowance Rebate System (CARS) program.

Homebrewing

Sodium silicate flocculant properties are also used to clarify wine and beer by precipitating colloidal particles. But as a clearing agent sodium silicate (water glass) is sometimes confused with isinglass which is prepared from collagen extracted from the dried swim bladders of sturgeon and other fishes. Eggs preserved in a bucket of waterglass gel, and their shells, are sometimes also used (baked and crushed) to clear wine.

Aquaculture

Sodium silicate gel is also used as a substrate for algal growth in aquaculture hatcheries.

Safe construction

A mixture of sodium silicate and sawdust has been used in between the double skin of certain safes. This not only makes them more fire resistant, but also makes cutting them open with an oxyacetylene torch extremely difficult due to the smoke emitted.
Crystal gardens

When crystals of a number of metallic salts are dropped into a solution of water glass, simple or branching stalagmites of coloured metal silicates are formed. This phenomenon has been used by manufacturers of toys and chemistry sets to provide instructive enjoyment to many generations of children from the early 20th century till the present. An early mention of crystals of metallic salts forming a "chemical garden" in sodium silicate is found in the 1946 Modern Mechanix magazine.[16] Metal salts used included the sulfates and/or chlorides of copper, cobalt, iron, nickel and manganese.

Pottery

Sodium Silicate is used to create a crackle effect in pottery, usually wheel-thrown. A vase or bottle is thrown on the wheel, fairly narrow and with thick walls. Sodium silicate is brushed on a section of the piece. After 5 minutes, the wall of the piece is stretched outward with a rib or hand. The result is a wrinkled or cracked look.
Sealing of leaking water containing structures

Sodium silicate with additives was injected into the ground in order to harden it and thereby to prevent further leakage of highly radioactive water from the Fukushima Daiichi nuclear power plant in Japan in April, 2011.[17] The residual heat carried by the water used for cooling the damaged reactors accelerated the setting of the injected mixture.

On June 3, 1958, the USS Nautilus, the world's first nuclear submarine, visited Everett and Seattle. In Seattle, crewmen dressed in civilian clothing, were sent in to secretly buy 140 quarts of an automotive product containing sodium silicate (originally identified as Stop Leak) to repair a leaking condenser system. The Nautilus was en route to the North Pole on a Top Secret mission to cross the North Pole submerged.

Cartridges

A historical use of the adhesive properties of sodium silicates is the production of paper cartridges for black powder revolvers produced by Colt's Manufacturing Company during the period from 1851 until 1873, especially during the American Civil War. Sodium silicate was used to seal combustible nitrated paper together to form a conical paper cartridge to hold the black powder, as well as to cement the lead ball or conical bullet into the open end of the paper cartridge. Such sodium silicate cemented paper cartridges were inserted into the cylinders of revolvers, thereby speeding the reloading of cap and ball black powder revolvers. This use largely ended with the introduction of Colt revolvers employing brass-cased cartridges starting in 1873.[19][20] Similarly, sodium silicate was also used to cement the top wad into brass shotgun shells, thereby eliminating any need for a crimp at the top of the brass shotgun shell to hold a shotgun shell together. Reloading brass shotgun shells was widely practiced by self-reliant American farmers during the 1870s, using the same waterglass material that was also used to preserve eggs. The cementing of the top wad on a shotgun shell consisted of applying from 3 to 5 drops of waterglass on the top wad to secure it to the brass hull. Brass hulls for shotgun shells were superseded by paper hulls starting around 1877. The newer paper-hulled shotgun shells used a roll crimp in place of a waterglass cemented joint to hold the top wad in the shell. However, whereas brass shotshells with top wads cemented with waterglass could be reloaded nearly indefinitely (given powder, wad, and shot, of course), the paper hulls that replaced the brass hulls could be reloaded only a few times.